Liao Wei-Yin, Lee Yuan-Gee, Huang Chun-Yueh, Lin Huan-Yu, Weng Yu-Ching, Chou Tse-Chuan
Department of Chemical Engineering, National Cheng Kung University, Tainan 701, Taiwan.
Biosens Bioelectron. 2004 Oct 15;20(3):482-90. doi: 10.1016/j.bios.2004.02.014.
A telemetric system was designed and constructed to sense pH and ethanol variation in aqueous solutions. The measured signals were transferred by software digitally and transmitted wirelessly by the telemeter, personal digital assistant (PDA), through the General Packet Radio Service (GPRS) protocol. The pH sensing electrode was designed to measure a chemical potential induced by a proton concentration gradient on the electrode's surface which exhibits internal Donnon diffusion behavior, and a linear relationship between the electrical potential and pH was found. The result shows that the wireless sensing system allowed not only long-term usage and long-distance transmission but also with high accuracy (e.g. S.D. less than +/-2%). The telemetric system can also be modified to measure ethanol concentration in aqueous solution amperometrically. It was found that the sensitivity of that ex situ measurements matched those of in field measurements with negligible deviation, less than 4%.
设计并构建了一种遥测系统,用于检测水溶液中的pH值和乙醇变化。测量信号通过软件进行数字传输,并由遥测仪、个人数字助理(PDA)通过通用分组无线服务(GPRS)协议进行无线传输。pH传感电极旨在测量由电极表面质子浓度梯度引起的化学势,该电极表现出内部唐南扩散行为,并且发现电势与pH之间存在线性关系。结果表明,无线传感系统不仅允许长期使用和远距离传输,而且具有高精度(例如标准偏差小于+/-2%)。该遥测系统还可以进行修改,以安培法测量水溶液中的乙醇浓度。结果发现,非现场测量的灵敏度与现场测量的灵敏度相匹配,偏差可忽略不计,小于4%。