氧促进的钯（II）催化：通过烯基硼酸化合物与烯烃的交叉偶联实现简便的C(sp2)-C(sp2)键形成。
Oxygen-promoted palladium(II) catalysis: facile C(sp2)-C(sp2) bond formation via cross-coupling of alkenylboronic compounds and olefins.
作者信息
Yoon Cheol Hwan, Yoo Kyung Soo, Yi Sung Wook, Mishra Rajesh K, Jung Kyung Woon
机构信息
Department of Chemistry, University of South Florida (SCA 400), 4202 East Fowler Avenue, Tampa, Florida 33620, USA.
出版信息
Org Lett. 2004 Oct 28;6(22):4037-9. doi: 10.1021/ol0483192.
PMID:15496093
Abstract
[reaction: see text] Oxygen-promoted Pd(II) catalysis facilitated the synthesis of conjugated dienes by cross-coupling of alkenylboronic compounds and various olefins including highly substituted alkenes and cyclohexenone. Under mild conditions, these versatile reactions were efficient and highly stereoselective.
摘要
[反应：见正文] 氧促进的钯（II）催化通过烯基硼酸化合物与各种烯烃（包括高度取代的烯烃和环己烯酮）的交叉偶联促进了共轭二烯的合成。在温和条件下，这些通用反应高效且具有高度立体选择性。
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