钯催化呋喃与苯乙烯的脱氢偶联反应。
Palladium-catalyzed dehydrogenative coupling of furans with styrenes.
机构信息
Institut de Chimie Moléculaire de Reims, UMR 6229, CNRS-Université de Reims Champagne-Ardenne, UFR des Sciences exactes et naturelles, BP 1039, 51687 Reims Cedex 2, France.
出版信息
Org Lett. 2009 Sep 17;11(18):4096-9. doi: 10.1021/ol901570p.
PMID:19691352
Abstract
Under palladium(II)-catalyzed and oxidative conditions, the coupling of furans with styrenes leads to the formation of Heck-type products in medium to good yields. The reaction is highly regio- and stereoselective, giving trans-olefins predominantly.
摘要
在钯(II)催化和氧化条件下，呋喃与苯乙烯的偶联反应以中等到良好的收率生成 Heck 型产物。该反应具有高度的区域和立体选择性，主要生成反式烯烃。
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