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改性泥炭树脂颗粒对水溶液中铅和铜的吸附作用

The adsorption of lead and copper from aqueous solution on modified peat-resin particles.

作者信息

Sun Q Y, Lu P, Yang L Z

机构信息

Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008, China.

出版信息

Environ Geochem Health. 2004 Jun-Sep;26(2-3):311-7. doi: 10.1023/b:egah.0000039595.12014.6b.

Abstract

Raw peat was modified with sulfuric acid, then mixed modified with resin to prepare the modified peat-resin particles. Using the batch experimental systems, the removal of heavy metals (copper and lead) on the modified peat-resin particles was investigated. The data of the adsorption isotherm could be fitted by the Langmuir equation well. The adsorption rate of heavy metals on modified peat-resin particles was very swift. The removal processes of heavy metals on modified peat-resin particles could be well described by pseudo-second order model. The adsorption rate of lead was affected by the initial heavy metal concentration, initial pH, particle size, agitation speed and particle mass. In the adsorption of heavy metals (lead and copper) on the modified peat-resin particles, ion exchange was the major reaction mechanism. Desorption data showed that the lead adsorbed by modified peat-resin particle could be desorbed by 0.5 N or 1.0 N HNO3. The desorption rate was swift. The experiments indicated that the modified peat-resin particles have great potential for the removal of heavy metals from wastewater.

摘要

将生泥炭用硫酸改性,然后与树脂混合改性以制备改性泥炭 - 树脂颗粒。使用间歇式实验系统,研究了改性泥炭 - 树脂颗粒对重金属(铜和铅)的去除情况。吸附等温线数据能很好地用朗缪尔方程拟合。重金属在改性泥炭 - 树脂颗粒上的吸附速率非常快。改性泥炭 - 树脂颗粒上重金属的去除过程能用准二级模型很好地描述。铅的吸附速率受初始重金属浓度、初始pH值、粒径、搅拌速度和颗粒质量的影响。在改性泥炭 - 树脂颗粒对重金属(铅和铜)的吸附过程中,离子交换是主要反应机制。解吸数据表明,改性泥炭 - 树脂颗粒吸附的铅能用0.5 N或1.0 N硝酸解吸。解吸速率很快。实验表明,改性泥炭 - 树脂颗粒在去除废水中的重金属方面具有很大潜力。

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