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[酸性橙II从水溶液中吸附到改性泥炭-树脂颗粒上]

[Adsorption of acid orange II from aqueous solution onto modified peat-resin particles].

作者信息

Sun Qing-Ye, Yang Lin-Zhang

机构信息

Nanjing Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008, China.

出版信息

Huan Jing Ke Xue. 2007 Jun;28(6):1300-4.

Abstract

The adsorption of acid orange II onto modified peat-resin particles was examined in aqueous solution in a batch system. The Langmuir and Freundlich adsorption models were applied to describe the equilibrium isotherms. The pseudo-first-order, pseudo-second-order kinetic and the intraparticle diffusion models were used to describe the kinetic data. The results showed that both Langmuir and Freundlich adsorption models could be used to describe the adsorption of acid orange II onto modified peat-resin particles. The maximum adsorption capacity was 71.43 mg x g(-1). The data analysis indicated that the intraparticle diffusion model could fit the results of kinetic experiment well. The adsorption rate of acid orange II onto modified peat-resin particles is affected by the initial dye concentrations, sizes and doses of modified peat-resin particles and agitation rates. The surface of modified peat-resin particle is the major adsorption area.

摘要

在间歇系统中,研究了酸性橙II在改性泥炭树脂颗粒上的水溶液吸附情况。应用朗缪尔和弗伦德利希吸附模型来描述平衡等温线。采用伪一级、伪二级动力学和颗粒内扩散模型来描述动力学数据。结果表明,朗缪尔和弗伦德利希吸附模型均可用于描述酸性橙II在改性泥炭树脂颗粒上的吸附。最大吸附容量为71.43 mg x g(-1)。数据分析表明,颗粒内扩散模型能很好地拟合动力学实验结果。酸性橙II在改性泥炭树脂颗粒上的吸附速率受初始染料浓度、改性泥炭树脂颗粒的尺寸和剂量以及搅拌速率的影响。改性泥炭树脂颗粒表面是主要的吸附区域。

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