金属硼烷反应化学。一种由硼框架支撑的双金属实现的简便且可逆的双氧捕获：[(PMe2Ph)4(O2)Pt2B10H10]的结构
Metallaborane reaction chemistry. A facile and reversible dioxygen capture by a B-frame-supported bimetallic: structure of [(PMe2Ph)4(O2)Pt2B10H10].
作者信息
Bould Jonathan, McInnes Yvonne M, Carr Michael J, Kennedy John D
机构信息
The School of Chemistry of the University of Leeds, Leeds, England, UK LS2 9JT, EC.
出版信息
Chem Commun (Camb). 2004 Nov 7(21):2380-1. doi: 10.1039/b406974a. Epub 2004 Sep 23.
DOI:10.1039/b406974a
PMID:15514775
Abstract
[(PMe2Ph)4Pt2B10H10] reversibly takes up atmospheric dioxygen to give the fluxional dioxygen-dimetallaborane complex [(PMe2Ph)4(O2)Pt2B10H10], which has Pt-Pt 2.7143(3), Pt-O 2.141(4) and 2.151(4) and O-O 1.434(6)A.
摘要
[(二甲基苯基膦)₄Pt₂B₁₀H₁₀]可逆地吸收大气中的氧气，生成具有流动性的双氧-二金属硼烷配合物[(二甲基苯基膦)₄(O₂)Pt₂B₁₀H₁₀]，其Pt-Pt键长为2.7143(3) Å，Pt-O键长为2.141(4) Å和2.151(4) Å，O-O键长为1.434(6) Å。
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