[PtMe(iPr₃P)₂]⁺：一种具有螯合相互作用且能发生C-H活化反应的二价铂配合物。
[PtMe(iPr3P)2]+: a Pt(II) complex with an agostic interaction that undergoes C-H activation.
作者信息
Ingleson Michael J, Mahon Mary F, Weller Andrew S
机构信息
Department of Chemistry, University of Bath, Bath, UK BA2 7AY.
出版信息
Chem Commun (Camb). 2004 Nov 7(21):2398-9. doi: 10.1039/b410846a. Epub 2004 Sep 23.
DOI:10.1039/b410846a
PMID:15514784
Abstract
The T-shaped Pt(II) complex [PtMe(iPr3P)2][1-H-closo-CB11Me11], which is stabilised by an agostic interaction, undergoes acid-catalysed intramolecular C-H activation in the presence of THF to afford cyclometallated [Pt(THF)(iPr3P)(iPr2PCHMeCH2)][1-H-closo-CB11Me11].
摘要
通过一个agostic相互作用稳定的T形Pt(II)配合物[PtMe(iPr3P)2][1-H-closo-CB11Me11]，在四氢呋喃存在下发生酸催化的分子内C-H活化，得到环金属化的[Pt(THF)(iPr3P)(iPr2PCHMeCH2)][1-H-closo-CB11Me11]。
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