Ingleson Michael J, Mahon Mary F, Weller Andrew S
Department of Chemistry, University of Bath, Bath, UK BA2 7AY.
Chem Commun (Camb). 2004 Nov 7(21):2398-9. doi: 10.1039/b410846a. Epub 2004 Sep 23.
The T-shaped Pt(II) complex [PtMe(iPr3P)2][1-H-closo-CB11Me11], which is stabilised by an agostic interaction, undergoes acid-catalysed intramolecular C-H activation in the presence of THF to afford cyclometallated [Pt(THF)(iPr3P)(iPr2PCHMeCH2)][1-H-closo-CB11Me11].
通过一个agostic相互作用稳定的T形Pt(II)配合物[PtMe(iPr3P)2][1-H-closo-CB11Me11]，在四氢呋喃存在下发生酸催化的分子内C-H活化，得到环金属化的[Pt(THF)(iPr3P)(iPr2PCHMeCH2)][1-H-closo-CB11Me11]。
