Sun Keqiang, Zhang Haidong, Xia Haian, Lian Yuxiang, Li Ying, Feng Zhaochi, Ying Pinliang, Li Can
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China.
Chem Commun (Camb). 2004 Nov 7(21):2480-1. doi: 10.1039/b408854a. Epub 2004 Sep 16.
The concentration of alpha-oxygen which can oxidize methane to methanol and benzene to phenol at RT, increases linearly with the amount of introduced extraframework Al on Fe/ZSM-5 catalysts prepared by solid-state exchange of FeCl3 and AlCl3 with H-ZSM-5.
在室温下能够将甲烷氧化为甲醇并将苯氧化为苯酚的α-氧的浓度,随通过用FeCl₃和AlCl₃与H-ZSM-5进行固态交换制备的Fe/ZSM-5催化剂上引入的骨架外铝量呈线性增加。