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鞘氨醇单胞菌属菌株TTNP3对壬基酚单一异构体的降解会产生一种羟基化诱导的迁移产物。

Degradation of a nonylphenol single isomer by Sphingomonas sp. strain TTNP3 leads to a hydroxylation-induced migration product.

作者信息

Corvini P F X, Meesters R J W, Schäffer A, Schröder H F, Vinken R, Hollender J

机构信息

Department of Biology V, RWTH Aachen University, Aachen, Germany.

出版信息

Appl Environ Microbiol. 2004 Nov;70(11):6897-900. doi: 10.1128/AEM.70.11.6897-6900.2004.

DOI:10.1128/AEM.70.11.6897-6900.2004
PMID:15528560
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC525215/
Abstract

Sphingomonas sp. strain TTNP3 degrades 4(3',5'-dimethyl-3'-heptyl)-phenol and unidentified metabolites that were described previously. The chromatographic analyses of the synthesized reference compound and the metabolites led to their identification as 2(3',5'-dimethyl-3'-heptyl)-1,4-benzenediol. This finding indicates that the nonylphenol metabolism of this bacterium involves unconventional degradation pathways where an NIH shift mechanism occurs.

摘要

鞘氨醇单胞菌属菌株TTNP3可降解4(3',5'-二甲基-3'-庚基)苯酚及之前描述的未鉴定代谢物。对合成的参考化合物和代谢物进行色谱分析后，将它们鉴定为2(3',5'-二甲基-3'-庚基)-1,4-苯二酚。这一发现表明，该细菌的壬基酚代谢涉及发生NIH迁移机制的非常规降解途径。

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Microbial degradation of a single branched isomer of nonylphenol by Sphingomonas TTNP3.鞘氨醇单胞菌TTNP3对壬基酚单支链异构体的微生物降解作用
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