Deng Bin, Yao Jiyong, Ibers James A
Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208-3113, USA.
Acta Crystallogr C. 2004 Nov;60(Pt 11):i110-i112. doi: 10.1107/S0108270104024230. Epub 2004 Oct 22.
The crystal structures of two new quaternary compounds, viz. dicerium orthosilicate selenide and dicerium orthosilicate telluride, Ce(2)(SiO(4))Q (Q = Se or Te), have been determined from single-crystal X-ray diffraction data. Each structure comprises infinite chains of SiO(4) tetrahedra separated by Ce and Q atoms. The site symmetries are Ce m and 2, Si 2 and Q m. The O atoms are in general positions.
两种新型四元化合物,即原硅酸铈硒化物和原硅酸铈碲化物,Ce₂(SiO₄)Q(Q = Se或Te)的晶体结构已通过单晶X射线衍射数据确定。每种结构都包含由Ce和Q原子隔开的无限长的SiO₄四面体链。位点对称性为Ce m和2,Si 2和Q m。O原子处于一般位置。