锰（II）、钴（II）和镍（II）与席夫碱配合物的光谱和磁性研究。
Spectral and magnetic studies on manganese(II), cobalt(II) and nickel(II) complexes with Schiff bases.
作者信息
Chandra Sulekh, Kumar Umendra
机构信息
Department of Chemistry, Zakir Husain College, University of Delhi, J.L. Nehru Marg, New Delhi 110002, India.
出版信息
Spectrochim Acta A Mol Biomol Spectrosc. 2005 Jan 1;61(1-2):219-24. doi: 10.1016/j.saa.2004.03.036.
Mn(II), Co(II) and Ni(II) complexes of 2-methylcyclohexanone thiosemicarbazone(MCHTSC L(1)) and 2-methylcyclohexanone-(4)N-methyl-3-thiosemicarbazone (MCHMTSC L(2)), general composition [M(L)(2)X(2)] (where M = Mn(II), Co(II), Ni(II), L = L(1) or L(2) and X = Cl(-), NO(3)(-), and [(1/2)SO(4)(2-)) have been synthesized and characterized by elemental analysis, magnetic susceptibility measurements, UV-vis, IR, EPR, and mass spectral studies. Various physico-chemical techniques suggest an octahedral geometry for all the complexes.
2-甲基环己酮缩氨基硫脲（MCHTSC L(1)）和2-甲基环己酮-（4）N-甲基-3-缩氨基硫脲（MCHMTSC L(2)）的锰（II）、钴（II）和镍（II）配合物，通式为[M(L)(2)X(2)]（其中M = 锰（II）、钴（II）、镍（II），L = L(1)或L(2)，X = Cl(-)、NO(3)(-)和[(1/2)SO(4)(2-)]）已通过元素分析、磁化率测量、紫外可见光谱、红外光谱、电子顺磁共振光谱和质谱研究进行了合成与表征。各种物理化学技术表明所有配合物均为八面体几何构型。
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