单分子转化的超分子催化作用：自组装主体内的氮杂-Cope重排反应 - Suppr

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Supramolecular catalysis of a unimolecular transformation: aza-Cope rearrangement within a self-assembled host.

作者信息

Fiedler Dorothea, Bergman Robert G, Raymond Kenneth N

机构信息

Department of Chemistry, University of California, Berkeley, CA 94720-1460, USA.

出版信息

Angew Chem Int Ed Engl. 2004 Dec 10;43(48):6748-51. doi: 10.1002/anie.200461776.

DOI:10.1002/anie.200461776

PMID:15558640

Abstract

摘要

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Supramolecular catalysis of a unimolecular transformation: aza-Cope rearrangement within a self-assembled host.

作者信息

Fiedler Dorothea, Bergman Robert G, Raymond Kenneth N

机构信息

Department of Chemistry, University of California, Berkeley, CA 94720-1460, USA.

出版信息

Angew Chem Int Ed Engl. 2004 Dec 10;43(48):6748-51. doi: 10.1002/anie.200461776.

DOI:10.1002/anie.200461776

PMID:15558640

Abstract

摘要

相似文献

Supramolecular catalysis of a unimolecular transformation: aza-Cope rearrangement within a self-assembled host.

Angew Chem Int Ed Engl. 2004 Dec 10;43(48):6748-51. doi: 10.1002/anie.200461776.

Enantioselective catalysis of the aza-Cope rearrangement by a chiral supramolecular assembly.

J Am Chem Soc. 2009 Dec 9;131(48):17530-1. doi: 10.1021/ja906386w.

Supramolecular catalysis of unimolecular rearrangements: substrate scope and mechanistic insights.

J Am Chem Soc. 2006 Aug 9;128(31):10240-52. doi: 10.1021/ja062329b.

Aza Cope rearrangement of propargyl enammonium cations catalyzed by a self-assembled "nanozyme".

J Am Chem Soc. 2008 Aug 20;130(33):10977-83. doi: 10.1021/ja8013055. Epub 2008 Jul 25.

Palladium-catalyzed allylic transposition of (allyloxy) iminodiazaphospholidines: a formal [3,3]-aza-phospha-oxa-Cope sigmatropic rearrangement for the stereoselective synthesis of allylic amines.

J Am Chem Soc. 2005 Oct 26;127(42):14887-93. doi: 10.1021/ja054161k.

Selective molecular recognition, C-H bond activation, and catalysis in nanoscale reaction vessels.

Acc Chem Res. 2005 Apr;38(4):349-58. doi: 10.1021/ar040152p.

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J Am Chem Soc. 2006 Oct 11;128(40):13042-3. doi: 10.1021/ja064934k.

Supramolecular catalysis of orthoformate hydrolysis in basic solution: an enzyme-like mechanism.

J Am Chem Soc. 2008 Aug 27;130(34):11423-9. doi: 10.1021/ja802839v. Epub 2008 Aug 5.

引用本文的文献

Dissecting the Effects of Cage Structure in the Catalytic Activation of Imide Chlorenium-Ion Donors.

J Am Chem Soc. 2025 Apr 2;147(13):11456-11464. doi: 10.1021/jacs.5c01249. Epub 2025 Mar 21.

Photoswitchable Catalysis by a Self-Assembled Molecular Cage.

J Am Chem Soc. 2024 Aug 7;146(31):21196-21202. doi: 10.1021/jacs.4c04846. Epub 2024 Jul 25.

Origins of High-Activity Cage-Catalyzed Michael Addition.

J Am Chem Soc. 2024 Jul 17;146(28):19317-19326. doi: 10.1021/jacs.4c05160. Epub 2024 Jul 8.

Chiral BINOL-phosphate assembled single hexagonal nanotube in aqueous solution for confined rearrangement acceleration.

Nat Commun. 2024 Mar 30;15(1):2799. doi: 10.1038/s41467-024-47150-6.

-cage catalysis and initiation derived from photo-activating host-guest encapsulation.

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Angew Chem Int Ed Engl. 2022 Mar 7;61(11):e202117011. doi: 10.1002/anie.202117011. Epub 2022 Jan 27.

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Chem Asian J. 2021 Dec 1;16(23):3851-3863. doi: 10.1002/asia.202100968. Epub 2021 Oct 22.

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Chem Rev. 2020 Dec 23;120(24):13480-13544. doi: 10.1021/acs.chemrev.0c00672. Epub 2020 Nov 25.