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在用于生产波特兰水泥熟料的生料中添加赤泥。

Red mud addition in the raw meal for the production of Portland cement clinker.

作者信息

Tsakiridis P E, Agatzini-Leonardou S, Oustadakis P

机构信息

Department of Mining and Metallurgical Engineering, Laboratory of Metallurgy, National Technical University of Athens, Greece 9, Iroon Polytechniou Street, 15780 Zografou, Athens, Greece.

出版信息

J Hazard Mater. 2004 Dec 10;116(1-2):103-10. doi: 10.1016/j.jhazmat.2004.08.002.

Abstract

The aim of the present research work was to investigate the possibility of adding red mud, an alkaline leaching waste, which is obtained from bauxite during the Bayer process for alumina production, in the raw meal for the production of Portland cement clinker. For that reason, two samples of raw meals were prepared: one with ordinary raw materials, as a reference sample ((PC)Ref), and another with 3.5% red mud ((PC)R/M). The effect on the reactivity of the raw mix was evaluated on the basis of the unreacted lime content in samples sintered at 1350, 1400 and 1450 degrees C. Subsequently, the clinkers were produced by sintering the two raw meals at 1450 degrees C. The results of chemical and mineralogical analyses as well as the microscopic examination showed that the use of the red mud did not affect the mineralogical characteristics of the so produced Portland cement clinker. Furthermore, both clinkers were tested by determining the grindability, setting time, compressive strength and expansibility. The hydration products were examined by XRD analysis at 2, 7, 28 and 90 days. The results of the physico-mechanical tests showed that the addition of the red mud did not negatively affect the quality of the produced cement.

摘要

本研究工作的目的是探讨在用于生产波特兰水泥熟料的生料中添加赤泥(一种在拜耳法生产氧化铝过程中从铝土矿获得的碱性浸出废料)的可能性。因此,制备了两种生料样品:一种使用普通原料作为参考样品((PC)Ref),另一种含有3.5%的赤泥((PC)R/M)。基于在1350、1400和1450摄氏度下烧结的样品中未反应石灰的含量,评估了对生料混合物反应活性的影响。随后,通过在1450摄氏度下烧结这两种生料来生产熟料。化学和矿物学分析结果以及微观检查表明,使用赤泥不会影响如此生产的波特兰水泥熟料的矿物学特性。此外,通过测定粉磨性、凝结时间、抗压强度和膨胀性对两种熟料进行了测试。通过在2、7、28和90天进行XRD分析来检查水化产物。物理力学测试结果表明,添加赤泥不会对所生产水泥的质量产生负面影响。

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