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铝工业区及受赤泥污染土壤中总汞的测定

Determination of total mercury in aluminium industrial zones and soil contaminated with red mud.

作者信息

Rasulov Oqil, Zacharová Andrea, Schwarz Marián

机构信息

Faculty of Ecology and Environmental Sciences, Department of Environmental Engineering, Technical University in Zvolen, T. G. Masaryka 24, 960 53, Zvolen, Slovakia.

出版信息

Environ Monit Assess. 2017 Aug;189(8):388. doi: 10.1007/s10661-017-6079-z. Epub 2017 Jul 11.

DOI:10.1007/s10661-017-6079-z
PMID:28699117
Abstract

This study investigated total mercury contents in areas impacted by aluminium plants in Tajikistan and Slovakia and in one area flooded with red mud in Hungary. We present the first determination of total mercury contents in the near-top soil (0-10 and 10-20 cm) in Tajikistan and the first comparative investigation of Tajikistan-Slovakia-Hungary. The Tajik Aluminium Company (TALCO) is one of the leading producers of primary aluminium in Central Asia. In the past 30 years, the plant has been producing large volumes of industrial waste, resulting in negative impacts on soil, groundwater and air quality of the surrounding region. Mercury concentrations were significant in Slovakia and Hungary, 6 years after the flooding. In studied areas in Slovakia and Hungary, concentrations of total mercury exceeded the threshold limit value (TLV = 0.5 mg Hg kg). However, in Tajikistan, values were below the TLV (0.006-0.074 mg kg) and did not significantly vary between depths. Total Hg in Slovakia ranged from 0.057 to 0.668 mg kg and in Hungary from 0.029 to 1.275 mg kg. However, in the plots near to the red mud reservoir and the flooded area, Hg concentrations were higher in the upper layers than in the lower ones.

摘要

本研究调查了塔吉克斯坦和斯洛伐克受铝厂影响地区以及匈牙利一处被赤泥淹没地区的总汞含量。我们首次测定了塔吉克斯坦近表层土壤(0 - 10厘米和10 - 20厘米)中的总汞含量,并首次对塔吉克斯坦 - 斯洛伐克 - 匈牙利进行了对比研究。塔吉克铝业公司(TALCO)是中亚主要的原铝生产商之一。在过去30年里,该工厂产生了大量工业废料,对周边地区的土壤、地下水和空气质量造成了负面影响。洪水发生6年后,斯洛伐克和匈牙利的汞浓度显著升高。在斯洛伐克和匈牙利的研究区域,总汞浓度超过了阈值(TLV = 0.5毫克汞/千克)。然而,在塔吉克斯坦,汞含量低于阈值(0.006 - 0.074毫克/千克),且不同深度之间没有显著差异。斯洛伐克的总汞含量范围为0.057至0.668毫克/千克,匈牙利为0.029至1.275毫克/千克。然而,在靠近赤泥库和洪水区域的地块中,上层的汞浓度高于下层。

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本文引用的文献

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The use of red mud as an immobiliser for metal/metalloid-contaminated soil: A review.利用赤泥作为金属/类金属污染土壤的稳定剂:综述。
J Hazard Mater. 2017 Mar 5;325:17-30. doi: 10.1016/j.jhazmat.2016.11.073. Epub 2016 Nov 28.
2
Mercury in terrestrial forested systems with highly elevated mercury deposition in southwestern China: The risk to insects and potential release from wildfires.中国西南部汞沉降高度升高的陆地森林系统中的汞:对昆虫的风险及野火引发的潜在释放。
Environ Pollut. 2016 May;212:188-196. doi: 10.1016/j.envpol.2016.01.003. Epub 2016 Feb 1.
3
Use of red mud (bauxite residue) for the retention of aqueous inorganic mercury(II).
利用赤泥(铝土矿残渣)吸附水中的无机汞(II)。
Environ Sci Pollut Res Int. 2015 Nov;22(22):17550-68. doi: 10.1007/s11356-015-4901-0. Epub 2015 Jul 5.
4
Results of the clean-up operation to reduce pollution on flooded agricultural fields after the red mud spill in Hungary.匈牙利赤泥泄漏后,为减少受污染农田积水而开展的清理行动的结果。
Environ Sci Pollut Res Int. 2015 Jul;22(13):9849-57. doi: 10.1007/s11356-015-4158-7. Epub 2015 Feb 4.
5
Bioleaching of rare earth and radioactive elements from red mud using Penicillium tricolor RM-10.利用青霉 RM-10 从赤泥中生物浸出稀土和放射性元素。
Bioresour Technol. 2013 May;136:16-23. doi: 10.1016/j.biortech.2013.03.070. Epub 2013 Mar 20.
6
Fractionation and mobility of metals in bauxite red mud.铝土矿赤泥中金属的分馏和迁移。
Environ Sci Pollut Res Int. 2013 Nov;20(11):7787-802. doi: 10.1007/s11356-013-1477-4. Epub 2013 Jan 30.
7
Speciation of mercury in mine waste: case study of abandoned and active gold mine sites at the Bibiani-Anwiaso-Bekwai area of South Western Ghana.汞在矿山废物中的形态:加纳西南部比比亚尼-安瓦索-贝夸地区废弃和活跃金矿的案例研究。
Environ Monit Assess. 2012 Dec;184(12):7623-34. doi: 10.1007/s10661-012-2523-2. Epub 2012 Jan 21.
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Fractions and leaching characteristics of mercury in coal.煤中汞的赋存形态与浸出特性
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Mercury in soils and plants in an abandoned cinnabar mining area (SW Spain).西班牙西南部一个废弃朱砂矿区土壤和植物中的汞
J Hazard Mater. 2009 Sep 15;168(2-3):1319-24. doi: 10.1016/j.jhazmat.2009.03.009. Epub 2009 Mar 14.
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Atmospheric monitoring at abandoned mercury mine sites in Asturias (NW Spain).西班牙西北部阿斯图里亚斯废弃汞矿场的大气监测。
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