由质子化的1,1-二芳基肼光化学生成氮鎓离子。
Photochemical generation of nitrenium ions from protonated 1,1-diarylhydrazines.
作者信息
Winter Arthur H, Thomas Selina I, Kung Andrew C, Falvey Daniel E
机构信息
Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland 20742, USA.
出版信息
Org Lett. 2004 Dec 9;6(25):4671-4. doi: 10.1021/ol048250y.
PMID:15575657
Abstract
[reaction: see text] Laser flash photolysis experiments, chemical trapping studies, and time-dependent density functional theory calculations demonstrate that photolysis of protonated 1,1-diarylhydrazines generates N,N-diarylnitrenium ions.
摘要
[反应：见正文] 激光闪光光解实验、化学捕获研究以及含时密度泛函理论计算表明，质子化的1,1 - 二芳基肼的光解会生成N,N - 二芳基氮鎓离子。
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