Zhu Mingzhao, Zheng Nan
Department of Chemistry and Biochemistry, University of Arkansas, Fayetteville, AR 72701, USA, Fax +1(479)5754049.
Synthesis (Stuttg). 2011 Jul 1;2011(14):2223-2236. doi: 10.1055/s-0030-1260082. Epub 2011 Jun 21.
A photocatalytic system involving Ru(bpyrz)·2HO, visible light, and air has been developed for cleavage of the N-N bonds of hydrazines and hydrazides. This catalytic system is generally effective for N,N-disubstituted hydrazine and hydrazide derivatives, including arylhydrazides, -alkyl--arylhydrazines, and ,-diarylhydrazines. The utility of this cleavage reaction has been demonstrated by synthesizing a variety of secondary aromatic amines.
一种涉及Ru(bpyrz)·2HO、可见光和空气的光催化体系已被开发用于肼和酰肼中N-N键的断裂。该催化体系对N,N-二取代肼和酰肼衍生物通常有效，包括芳基酰肼、烷基-芳基肼和二芳基肼。通过合成多种仲芳胺证明了这种断裂反应的实用性。
