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富硫配位环境中锌的甲基、氢硫属化物和苯基硫属化物配合物：三（2-巯基-1-叔丁基咪唑基）硼氢化锌配合物[TmBut]ZnMe、[TmBut]ZnEH（E = S，Se）和[TmBut]ZnEPh（E = O，S，Se，Te）的合成与结构表征

Methyl, hydrochalcogenido, and phenylchalcogenolate complexes of zinc in a sulfur rich coordination environment: syntheses and structural characterization of the tris(2-mercapto-1-tert-butylimidazolyl)hydroboratozinc complexes [TmBut]ZnMe, [TmBut]ZnEH (E = S, Se) and [TmBut]ZnEPh (E = O, S, Se, Te).

作者信息

Melnick Jonathan G, Docrat Arefa, Parkin Gerard

机构信息

Department of Chemistry, Columbia University, New York, New York, 10027, USA.

出版信息

Chem Commun (Camb). 2004 Dec 21(24):2870-1. doi: 10.1039/b412218f. Epub 2004 Oct 25.

DOI:10.1039/b412218f
PMID:15599448
Abstract

A series of hydrochalcogenido and phenylchalcogenolate complexes of zinc supported by tris(2-mercapto-1-tert-butylimidazolyl)hydroborato ligation, [Tm(Bu(t))]ZnEH (E = S, Se) and [Tm(Bu(t))]ZnEPh (E = O, S, Se, Te) have been synthesized from [Tm(Bu(t))]ZnMe; structural characterization by X-ray diffraction indicates that the variation in Zn-E bonding as a function of the chalcogen is significantly different from that in other series of metal-chalcogenolate compounds.

摘要

通过三（2-巯基-1-叔丁基咪唑基）硼氢化配体[Tm(Bu(t))]支撑的一系列锌的氢硫属化物和苯基硫属化物配合物，即[Tm(Bu(t))]ZnEH（E = S，Se）和[Tm(Bu(t))]ZnEPh（E = O，S，Se，Te），由[Tm(Bu(t))]ZnMe合成；X射线衍射的结构表征表明，锌-硫属键随硫属元素的变化与其他系列金属硫属化物化合物中的情况有显著不同。

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