Reactivity of a N-heterocyclic carbene, 1,3-di-(1-adamantyl) imidazol-2-ylidene, with a pseudo-acid: structural characterization of Claisen condensation adduct.
作者信息
Grasa Gabriela A, Singh Rohit, Scott Natalie M, Stevens Edwin D, Nolan Steven P
机构信息
Department of Chemistry, University of New Orleans, New Orleans, LA-70148, USA.
出版信息
Chem Commun (Camb). 2004 Dec 21(24):2890-1. doi: 10.1039/b410986d. Epub 2004 Nov 4.
DOI:10.1039/b410986d
PMID:15599458
Abstract
The reactivity of a N-heterocyclic carbene (NHC) with a pseudo-acid (ester in this case) is described. The product results from an unusual C-H bond activation. The structure of the product has been established by a single crystal diffraction study.
摘要
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