Judd Ted C, Bischoff Alexander, Kishi Yoshito, Adusumilli Sarojini, Small Pamela L C
Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, USA.
Org Lett. 2004 Dec 23;6(26):4901-4. doi: 10.1021/ol0479996.
[structure: see text] By total synthesis, mycolactone C has been established as an approximately 1:1 mixture of Z-Delta4'5'- and E-Delta4'5'-geometric isomers of C12'-deoxymycolactones A and B.
[结构:见正文] 通过全合成,已确定霉菌内酯C是C12'-脱氧霉菌内酯A和B的Z-Δ4'5'-和E-Δ4'5'-几何异构体的大约1:1混合物。