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羟基化植物油脂肪酸甲酯对柴油润滑性的影响

Influence of fatty acid methyl esters from hydroxylated vegetable oils on diesel fuel lubricity.

作者信息

Goodrum John W, Geller Daniel P

机构信息

Department of Biological and Agricultural Engineering, University of Georgia, Athens, GA 30602, USA.

出版信息

Bioresour Technol. 2005 May;96(7):851-5. doi: 10.1016/j.biortech.2004.07.006.

Abstract

Current and future regulations on the sulfur content of diesel fuel have led to a decrease in lubricity of these fuels. This decreased lubricity poses a significant problem as it may lead to wear and damage of diesel engines, primarily fuel injection systems. Vegetable oil based diesel fuel substitutes (biodiesel) have been shown to be clean and effective and may increase overall lubricity when added to diesel fuel at nominally low levels. Previous studies on castor oil suggest that its uniquely high level of the hydroxy fatty acid ricinoleic acid may impart increased lubricity to the oil and its derivatives as compared to other vegetable oils. Likewise, the developing oilseed Lesquerella may also increase diesel lubricity through its unique hydroxy fatty acid composition. This study examines the effect of castor and Lesquerella oil esters on the lubricity of diesel fuel using the High-Frequency Reciprocating Rig (HFRR) test and compares these results to those for the commercial vegetable oil derivatives soybean and rapeseed methyl esters.

摘要

当前及未来对柴油含硫量的规定导致了这些燃料润滑性的降低。这种降低的润滑性带来了一个重大问题,因为它可能导致柴油发动机,主要是燃油喷射系统的磨损和损坏。基于植物油的柴油燃料替代品(生物柴油)已被证明是清洁且有效的,并且在以名义上较低的水平添加到柴油中时可能会提高整体润滑性。先前对蓖麻油的研究表明,与其他植物油相比,其独特的高含量羟基脂肪酸蓖麻油酸可能会使该油及其衍生物的润滑性增加。同样,正在开发的油籽莱斯奎勒油也可能因其独特的羟基脂肪酸组成而提高柴油的润滑性。本研究使用高频往复试验机(HFRR)测试来检验蓖麻油和莱斯奎勒油酯对柴油润滑性的影响,并将这些结果与商业植物油衍生物大豆甲酯和油菜籽甲酯的结果进行比较。

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