Ag(I)与3,6-双(2-吡啶基)-1,2,4,5-四嗪(bptz)反应的阴离子依赖性：分子螺旋桨化合物[Ag2(bptz)3][AsF6]2的分离
Anion dependence of Ag(I) reactions with 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine (bptz): isolation of the molecular propeller compound [Ag2(bptz)3][AsF6]2.
作者信息
Schottel Brandi L, Bacsa John, Dunbar Kim R
机构信息
Department of Chemistry, Texas A&M University, PO Box 30012, College Station, Texas 77842-3012, USA.
出版信息
Chem Commun (Camb). 2005 Jan 7(1):46-7. doi: 10.1039/b410811f. Epub 2004 Nov 19.
DOI:10.1039/b410811f
PMID:15614367
Abstract
The new compound [Ag(2)(bptz)(3)]AsF(6), prepared from the reaction of bptz with Ag[AsF(6)] in CH(3)CN, is stable in solution as well as the solid-state and exhibits an unprecedented propeller arrangement of three bptz ligands spanning two Ag(i) ions with AsF(6) anions located in the folds of the cation.
摘要
由bptz与Ag[AsF₆]在乙腈中反应制备的新化合物[Ag₂(bptz)₃][AsF₆]₂，在溶液和固态中均稳定，并且呈现出一种前所未有的螺旋桨排列，即三个bptz配体跨越两个Ag⁺离子，[AsF₆]⁻阴离子位于阳离子的褶皱处。
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