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Enantioselective catalysis of the hetero-Diels-Alder reaction between Brassard's diene and aldehydes by hydrogen-bonding activation: a one-step synthesis of (S)-(+)-dihydrokawain.
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Organocatalyzed asymmetric alpha-aminoxylation of aldehydes and ketones--an efficient access to enantiomerically pure alpha-hydroxycarbonyl compounds, diols, and even amino alcohols.
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