Borkovec M
Federal Institute of Technology, Zürich, Switzerland.
Adv Colloid Interface Sci. 1992 Mar 16;37(3-4):195-217. doi: 10.1016/0001-8686(92)80084-b.
Simple phenomenological theory of noninteracting microemulsion water droplets dispersed in an oil phase (or vice versa) is presented. Several characteristics quantities such as radii, polydispersities, shape fluctuation amplitudes and interfacial tensions are evaluated. In particular, the different features of a one phase microemulsion and a two phase coexistence of the microemulsion with an excess water phase are emphasized. We discuss the relations to most existent theories of microemulsion droplets, micelles and nucleating droplets and briefly review recent experimental techniques to access the relevant parameters.
本文提出了一种关于分散在油相中的非相互作用微乳液水滴(或反之亦然)的简单唯象理论。评估了几个特征量,如半径、多分散性、形状波动幅度和界面张力。特别强调了单相微乳液以及微乳液与过量水相两相共存的不同特征。我们讨论了与现有的大多数微乳液液滴、胶束和成核液滴理论的关系,并简要回顾了获取相关参数的最新实验技术。