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老化玻璃颗粒/树脂基质牙科复合材料中钡和锶的浸出

Barium and strontium leaching from aged glass particle/resin matrix dental composites.

作者信息

Zhou Manshui, Drummond James L, Hanley Luke

机构信息

Department of Chemistry (M/C 111), University of Illinois at Chicago, 4500 SES, 845 West Taylor Street, Chicago, IL 60607-7061, USA.

出版信息

Dent Mater. 2005 Feb;21(2):145-55. doi: 10.1016/j.dental.2004.02.009.

Abstract

OBJECTIVES

This study characterizes the loss of Ba and Sr from glass particle/resin-matrix dental composites during simulated aging.

METHODS

X-ray wavelength dispersive spectrometry and secondary ion mass spectrometry were used to analyze the Ba and Sr content from the surfaces of three commercial dental composites after aging for 4 and 8 months in humid air, artificial saliva, water, and 50% ethanol.

RESULTS

Aging in artificial saliva caused the greatest leaching of Ba or Sr for all the specimens, compared with either lesser or no leaching for aging in ethanol and water. Differences in leaching were observed between the different composites. Composites aged in artificial saliva also picked up elements in the saliva solution and displayed crystallite formation on the surface. Samples aged in ethanol displayed cracking which was not observed for water or artificial saliva.

SIGNIFICANCE

Dental composites display ion leaching from their surfaces over periods of four to eight months. Three mechanisms are proposed to explain differences in leaching for the various composites and aging solutions. Surface mineralization is also proposed to occur as a self-repair mechanism in artificial saliva.

摘要

目的

本研究对模拟老化过程中牙科玻璃颗粒/树脂基质复合材料中钡和锶的损失情况进行了表征。

方法

采用X射线波长色散光谱法和二次离子质谱法,分析了三种商用牙科复合材料在潮湿空气中、人工唾液、水和50%乙醇中老化4个月和8个月后表面的钡和锶含量。

结果

与在乙醇和水中老化相比,在人工唾液中老化导致所有试样中钡或锶的浸出量最大,乙醇和水中老化的浸出量较少或无浸出。不同复合材料之间观察到浸出差异。在人工唾液中老化的复合材料还从唾液溶液中摄取元素,并在表面形成微晶。在乙醇中老化的样品出现开裂,而在水或人工唾液中未观察到这种情况。

意义

牙科复合材料在四到八个月的时间里会从其表面浸出离子。提出了三种机制来解释各种复合材料和老化溶液在浸出方面的差异。还提出在人工唾液中会发生表面矿化,作为一种自我修复机制。

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