Talluri Siva Kumar, Sudalai Arumugam
Chemical Engineering & Process Development Division, National Chemical Laboratory, Pashan Road, Pune, India 411008.
Org Lett. 2005 Mar 3;7(5):855-7. doi: 10.1021/ol047402m.
N-Bromosuccinimide efficiently catalyzes the hydroamination and hydroalkoxylation of activated styrenes using tosylamides, carbamates, and alcohols as the nucleophiles to afford amino and ether derivatives, respectively. Both the processes give good to excellent yields of the products with 100% regioselectivity (Markovnikov fashion). [structure: see text]
N-溴代琥珀酰亚胺能高效催化活化苯乙烯的氢胺化反应和氢烷氧基化反应，分别使用对甲苯磺酰胺、氨基甲酸酯和醇作为亲核试剂，得到氨基衍生物和醚衍生物。这两个过程都能以良好至优异的产率得到产物，区域选择性为100%（符合马氏规则）。[结构：见正文]
