羧酸盐的轴向配位激活了非血红素FeIV=O单元。 - Suppr

Axial coordination of carboxylate activates the non-heme FeIV=O unit.

作者信息

Rohde Jan-Uwe, Que Lawrence

机构信息

Department of Chemistry and Center for Metals in Biocatalysis, University of Minnesota, 207 Pleasant Street SE, Minneapolis, MN 55455, USA.

出版信息

Angew Chem Int Ed Engl. 2005 Apr 8;44(15):2255-8. doi: 10.1002/anie.200462631.

DOI:10.1002/anie.200462631

PMID:15739239

Abstract

摘要

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Axial coordination of carboxylate activates the non-heme FeIV=O unit.羧酸盐的轴向配位激活了非血红素FeIV=O单元。

Angew Chem Int Ed Engl. 2005 Apr 8;44(15):2255-8. doi: 10.1002/anie.200462631.

Comparison of FeIV=O heme and non-heme species: electronic structures, bonding, and reactivities.FeIV=O血红素与非血红素物种的比较：电子结构、键合和反应性。

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Spectroscopic and quantum chemical characterization of the electronic structure and bonding in a non-heme FeIV[double bond]O complex.非血红素FeIV=O配合物中电子结构和键合的光谱及量子化学表征

J Am Chem Soc. 2004 May 5;126(17):5378-9. doi: 10.1021/ja0498033.

Tetranuclear iron(III) complexes of an octadentate pyridine-carboxylate ligand and their catalytic activity in alkane oxidation by hydrogen peroxide.一种八齿吡啶羧酸配体的四核铁（III）配合物及其在过氧化氢氧化烷烃中的催化活性。

Dalton Trans. 2006 Jan 21(3):492-501. doi: 10.1039/b512069a. Epub 2005 Oct 10.

Synthetic models for non-heme carboxylate-bridged diiron metalloproteins: strategies and tactics.非血红素羧酸盐桥联二铁金属蛋白的合成模型：策略与方法

Chem Rev. 2004 Feb;104(2):987-1012. doi: 10.1021/cr020622y.

Differences in and comparison of the catalytic properties of heme and non-heme enzymes with a central oxo-iron group.含中心氧代铁基团的血红素酶和非血红素酶催化特性的差异与比较。

Angew Chem Int Ed Engl. 2006 Mar 3;45(11):1790-3. doi: 10.1002/anie.200503841.

Oxidative N-dealkylation reactions by oxoiron(IV) complexes of nonheme and heme ligands.非血红素和血红素配体的氧合铁（IV）配合物引发的氧化N-脱烷基反应。

Inorg Chem. 2007 Jan 8;46(1):293-8. doi: 10.1021/ic0614014.

Axial ligand substituted nonheme FeIV=O complexes: observation of near-UV LMCT bands and Fe=O Raman vibrations.轴向配体取代的非血红素FeIV=O配合物：近紫外配体到金属电荷转移带和Fe=O拉曼振动的观测

J Am Chem Soc. 2005 Sep 14;127(36):12494-5. doi: 10.1021/ja0540573.

Kinetics and mechanisms of formation and reactivity of non-heme iron oxygen intermediates.非血红素铁氧中间体的形成动力学、机制及反应活性

Chem Rev. 2005 Jun;105(6):2175-226. doi: 10.1021/cr030709z.

Unexpected kinetic complexity in the formation of a nonheme oxoiron(IV) complex.非血红素氧代铁（IV）配合物形成过程中意外的动力学复杂性。

Chem Commun (Camb). 2008 May 21(19):2209-11. doi: 10.1039/b716036d. Epub 2008 Mar 27.

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[Fe(IV)═O(TBC)(CH3CN)]2+: comparative reactivity of iron(IV)-oxo species with constrained equatorial cyclam ligation.\[ \begin{align*} [Fe(IV)═O(TBC)(CH_3CN)]^{2+}:& \text{comparative reactivity of iron(IV)-oxo species with constrained equatorial cyclam ligation.} \end{align*} \]

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Axial coordination of carboxylate activates the non-heme FeIV=O unit.

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