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[气相色谱/质谱联用(GC/MS)法分析催化裂化轻汽油醚化后产物中的醚类及相关烯烃]

[Analysis of ethers and related olefines in light gasoline from catalytic cracking after etherification by gas chromatography/mass spectrometry (GC/MS)].

作者信息

Li Z, Zheng J

机构信息

Analysis Centre of Fushun Petroleum Institute, Fushun, 113001.

出版信息

Se Pu. 1997 May;15(3):250-1.

Abstract

A method for qualitative and quantitative analysis by GC/MS and GC of ethers and related olefines in light gasoline from catalytic cracking before and after etherification has been presented. By means of the analysis of the reactive olefines and the ethers produced it is concluded that six kinds of olefines had taken part in the etherification process, they were, 2-methyl propene-1,2-methyl butene-2,2-methyl butene-1,2-methyl pentene-1,2-ethyl butene-1, and 2-methyl pentene-2, and the four ethers produced were 2-methoxy-2-methyl propane, 2-methoxy-2-methyl butane, 2-methoxy-2-methyl pentane and 3-methoxy-3-methyl pentane. These ethers are all contributing to enhance the octane number.

摘要

介绍了一种用气相色谱/质谱联用仪(GC/MS)和气相色谱(GC)对催化裂化轻质汽油醚化前后的醚类及相关烯烃进行定性和定量分析的方法。通过对反应性烯烃和生成的醚类进行分析得出,有六种烯烃参与了醚化过程,它们是2-甲基丙烯-1、2-甲基丁烯-2、2-甲基丁烯-1、2-甲基戊烯-1、2-乙基丁烯-1和2-甲基戊烯-2,生成的四种醚类是2-甲氧基-2-甲基丙烷、2-甲氧基-2-甲基丁烷、2-甲氧基-2-甲基戊烷和3-甲氧基-3-甲基戊烷。这些醚类都有助于提高辛烷值。

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