从头孢菌素及其3:1铁配合物的全合成到铁（III）、头孢菌素和绿脓菌素之间1:1:1混合配合物的分离。
From a total synthesis of cepabactin and its 3:1 ferric complex to the isolation of a 1:1:1 mixed complex between iron (III), cepabactin and pyochelin.
作者信息
Klumpp Cédric, Burger Alain, Mislin Gaëtan L, Abdallah Mohamed A
机构信息
Métaux et Microorganismes: Chimie, Biologie et Applications, Département des Récepteurs et Protéines Membranaires (CNRS UPR 9050), Ecole Supérieure de Biotechnologie de Strasbourg, Boulevard Sébastien Brant, F-67400 Illkirch, France.
出版信息
Bioorg Med Chem Lett. 2005 Mar 15;15(6):1721-4. doi: 10.1016/j.bmcl.2005.01.034.
A novel and straightforward total synthesis of cepabactin and its iron (III) complex is described. The latter compound was compared and identified to that obtained from the cultures of Burkholderia cepacia. On treatment of the growth medium of two different strains of B. cepacia with ferric chloride, we have isolated and characterized an unexpected mixed complex of iron (III), cepabactin and pyochelin.
描述了一种新颖且简便的头孢菌素及其铁（III）配合物的全合成方法。将后一种化合物与从洋葱伯克霍尔德菌培养物中获得的化合物进行了比较和鉴定。在用氯化铁处理两种不同洋葱伯克霍尔德菌菌株的生长培养基后，我们分离并表征了一种意外的铁（III）、头孢菌素和绿脓菌素混合配合物。
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