Hui Rui-hua, Hou Dong-yan, Guan Chong-xin
Analytical and Testing Research Center, Anshan Normal University, Anshan 114005, China.
Guang Pu Xue Yu Guang Pu Fen Xi. 2004 Sep;24(9):1106-9.
A new spectrophotometric method for the determination of germanium in A. arborescens was developed. The method was based on the fact that germanium forms a stable complex with phenylfluorone in the acidified solution with CTMAB as solubilization agent. The maximum absorption of association complex is at 530 nm, the linear range is 0.1-0.7 microg x mL(-1), the regression equation is A = 0.0817 + 0.8677c530, (microg x mL(-1)) the correlation coefficient r=0.9177, and the limit of detection is 0.65 microg x mL(-1). The leaves and stems of A. arborescens were determined by the proposed method. The total amount of germanium is 697.0-1219.5 ng x g(-1), and the content of organic Ge is 95.45%-98.99%. The method is suitable for the analysis of samples which contain both organic Ge and inorganic Ge.
建立了一种新的分光光度法测定乔木状马蓝中的锗。该方法基于锗在以十六烷基三甲基溴化铵为增溶剂的酸化溶液中与苯基荧光酮形成稳定络合物这一事实。缔合络合物的最大吸收波长为530nm,线性范围为0.1 - 0.7μg·mL⁻¹,回归方程为A = 0.0817 + 0.8677c530(μg·mL⁻¹),相关系数r = 0.9177,检出限为0.65μg·mL⁻¹。采用该方法对乔木状马蓝的叶和茎进行了测定。锗的总量为697.0 - 1219.5 ng·g⁻¹,有机锗含量为95.45% - 98.99%。该方法适用于同时含有有机锗和无机锗的样品分析。