[三种金属酞菁的三阶非线性光学性质]

[Third order nonlinear optical properties of three kinds of metal phthalocyanines].

作者信息

Li Lin, Huang Yan-ping, Li Shan-shan, Dai Yu-wen

机构信息

Key Laboratory for Optical and Magnetic Resonance Spectroscopy, Department of Physics, East China Normal University, Shanghai 200062, China.

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2004 Feb;24(2):149-51.

PMID:15769002

Abstract

Using YAG laser, the nonlinear optical refractive indexes of three kinds of metal phthalocyanines in DMF, ZnPCS(C6H32N8S4Zn), AlPCS (C56H32AlClN8S4) and AlPCP (C6H32AlClN8O4) were studied with the method of Z-scan. Their third-order susceptibilities chi(3) were also calculated. The result shows that different central ion and different substituents could affect their third-order susceptibilities. The mechanisms of third order optical nonlinearity and energy transfer in the photodynamic therapy were discussed.

摘要

采用YAG激光，运用Z扫描方法研究了三种金属酞菁化合物ZnPCS（C6H32N8S4Zn）、AlPCS（C56H32AlClN8S4）和AlPCP（C6H32AlClN8O4）在N，N-二甲基甲酰胺（DMF）中的非线性光学折射率，并计算了它们的三阶极化率χ(3)。结果表明，中心离子和取代基的不同会影响其三阶极化率。探讨了三阶光学非线性及光动力治疗中的能量转移机制。