Using particle shape to induce tilted and bistable liquid crystal anchoring.

We use Monte Carlo simulations of hard Gaussian overlap (HGO) particles symmetrically confined in slab geometry to investigate the role of particle-substrate interactions on liquid crystalline anchoring. Despite the restriction here to purely steric interactions and smooth substrates, a range of behaviors are captured, including tilted anchoring and homeotropic-planar bistability. These macroscopic behaviors are all achieved through appropriate tuning of the microscopics of the HGO-substrate interaction, based upon nonadditive descriptions for the HGO-substrate shape parameter.