Steel Peter J
Department of Chemistry, College of Science, University of Canterbury, Christchurch, New Zealand.
Acc Chem Res. 2005 Apr;38(4):243-50. doi: 10.1021/ar040166v.
Metallosupramolecular chemistry involves the use of combinations of organic ligands and metals for the construction of both discrete and polymeric aggregates. This Account describes some lessons that we have learned about aspects of ligand design in the course of our work in this area. Specifically, we recommend the incorporation of a diverse range of heterocyclic rings and arene cores within the ligands, as well as attention to symmetry considerations, and offer suggestions for the introduction of chirality and flexibility within the ligands and the exploitation of other weak interactions to assist self-assembly processes.
金属超分子化学涉及使用有机配体和金属的组合来构建离散和聚合聚集体。本综述介绍了我们在该领域工作过程中在配体设计方面所学到的一些经验教训。具体而言，我们建议在配体中引入多种杂环和芳烃核心，同时关注对称性因素，并就配体内手性和灵活性的引入以及利用其他弱相互作用辅助自组装过程提供建议。
