Bradshaw D, Claridge J B, Cussen E J, Prior T J, Rosseinsky M J
Department of Chemistry, University of Liverpool, Liverpool L69 7ZD, U.K.
Acc Chem Res. 2005 Apr;38(4):273-82. doi: 10.1021/ar0401606.
Scientific and technological interest in porous materials with molecule-sized channels and cavities has led to an intense search for controlled chemical routes to systems with specific properties. This Account details our work on directing the assembly of open-framework structures based on molecules and investigating how the response of nanoporous examples of such materials to guests differs from classical rigid porous systems. The stabilization of chiral nanoporosity by a hierarchy of interactions that both direct and maintain a helical open-framework structure exemplifies the approach.
对具有分子尺寸通道和空腔的多孔材料的科技兴趣，引发了人们对具有特定性质的系统的可控化学合成路线的深入探索。本综述详细介绍了我们在指导基于分子的开放框架结构组装方面的工作，以及研究这类材料的纳米多孔实例对客体的响应与传统刚性多孔体系有何不同。通过一系列既能引导又能维持螺旋开放框架结构的相互作用来实现手性纳米孔隙度的稳定，就是这种方法的一个例证。
