新型β-二酮酸酯类配体的铕（III）和铽（III）配合物的合成、红外光谱及荧光光谱研究

Studies on synthesis, infrared and fluorescence spectra of new europium (III) and terbium (III) complexes with an beta-diketonate-type ligand.

作者信息

Tai Xi-Shi, Tan Min-Yu

机构信息

Department of Chemistry, Weifang University, Weifang 261061, PR China.

出版信息

Spectrochim Acta A Mol Biomol Spectrosc. 2005 Jun;61(8):1767-70. doi: 10.1016/j.saa.2004.07.006.

DOI:10.1016/j.saa.2004.07.006

PMID:15863045

Abstract

A new beta-diketonate-type ligand, N-(2-amino-6-methyl-pyridinyl)ketoacetamide (L) and its complexes with europium (III) and terbium (III) were synthesized. The complexes were characterized by elemental analysis, infrared spectra and conductivity. The europium (III) and terbium (III)-ions were found to coordinate to the CO oxygen atoms and pyridine nitrogen atoms. The fluorescence properties of these complexes in solid, DMF and CH3OH were studied. The solvent factors influencing the fluorescent intensity are discussed.

摘要

合成了一种新型β-二酮类配体N-(2-氨基-6-甲基吡啶基)酮乙酰胺(L)及其与铕(III)和铽(III)的配合物。通过元素分析、红外光谱和电导率对配合物进行了表征。发现铕(III)和铽(III)离子与羰基氧原子和吡啶氮原子配位。研究了这些配合物在固体、N,N-二甲基甲酰胺和甲醇中的荧光性质。讨论了影响荧光强度的溶剂因素。

相似文献

Studies on synthesis, infrared and fluorescence spectra of new europium (III) and terbium (III) complexes with an beta-diketonate-type ligand.新型β-二酮酸酯类配体的铕（III）和铽（III）配合物的合成、红外光谱及荧光光谱研究

Spectrochim Acta A Mol Biomol Spectrosc. 2005 Jun;61(8):1767-70. doi: 10.1016/j.saa.2004.07.006.

Synthesis and infrared and fluorescence spectra of new europium and terbium polynuclear complexes with an amide-based 1,10-phenanthroline derivative.新型铕和铽多核配合物与酰胺基-1,10-菲咯啉衍生物的合成及其红外光谱和荧光光谱

Spectrochim Acta A Mol Biomol Spectrosc. 2004 Jul;60(8-9):1707-11. doi: 10.1016/j.saa.2003.09.009.

Solvent effect on the luminescent properties of new europium and terbium nitrate complexes with 3,3,7,7-tetra[N-methyl-N-phenyl(acetamide)-2-oxymethyl]-5-oxanonane.溶剂对新型铕和铽硝酸盐与3,3,7,7-四[N-甲基-N-苯基（乙酰胺）-2-氧甲基]-5-氧杂壬烷配合物发光性质的影响

Spectrochim Acta A Mol Biomol Spectrosc. 2007 Mar;66(3):590-3. doi: 10.1016/j.saa.2006.03.041. Epub 2006 Apr 19.

Anion effects on the fluorescence spectra of europium and terbium complexes with a family of ether-amide type multipodal ligands.

Spectrochim Acta A Mol Biomol Spectrosc. 2007 Mar;66(3):662-6. doi: 10.1016/j.saa.2006.04.008. Epub 2006 Apr 29.

Synthesis and infrared and luminescence spectra of rare earth complexes with a new hexapodal ligand.新型六齿配体稀土配合物的合成及其红外光谱与发光光谱

Spectrochim Acta A Mol Biomol Spectrosc. 2006 Jan;63(1):164-8. doi: 10.1016/j.saa.2005.04.045. Epub 2005 Dec 5.

Luminescent properties of solvent effect for europium and terbium nitrate complexes with 3,3,7,7-tetra[N-benzyl-N-phenyl(acetamide)-2-oxymethyl]-5-oxanonane.硝酸铕和硝酸铽与3,3,7,7-四[N-苄基-N-苯基（乙酰胺基）-2-氧甲基]-5-氧杂壬烷配合物的溶剂效应发光性质

Spectrochim Acta A Mol Biomol Spectrosc. 2007 Feb;66(2):377-80. doi: 10.1016/j.saa.2006.03.012. Epub 2006 Mar 10.

Conformation effects on the fluorescence spectra of europium and terbium complexes with a family of ether-amide type multipodal ligands.构象对铕和铽与一族醚酰胺型多齿配体配合物荧光光谱的影响。

Spectrochim Acta A Mol Biomol Spectrosc. 2007 Jan;66(1):118-25. doi: 10.1016/j.saa.2006.01.053. Epub 2006 Feb 28.

[Fluorescence studies on the mixed solid complexes of europium and terbium].铕和铽混合固体配合物的荧光研究

Guang Pu Xue Yu Guang Pu Fen Xi. 2000 Oct;20(5):718-20.

Synthesis, infrared and fluorescence spectra of lanthanide complexes with a new amide-based 1,3,4-oxadiazole derivative.镧系元素与一种新型酰胺基-1,3,4-恶二唑衍生物配合物的合成、红外光谱和荧光光谱

Spectrochim Acta A Mol Biomol Spectrosc. 2007 Oct;68(2):349-53. doi: 10.1016/j.saa.2006.11.044. Epub 2006 Dec 8.

Synthesis and luminescent properties of the lanthanide isothiocyanate complexes with an amide-type tripodal ligand.镧系异硫氰酸酯与酰胺型三脚架配体配合物的合成及发光性质

Spectrochim Acta A Mol Biomol Spectrosc. 2007 Jul;67(3-4):858-63. doi: 10.1016/j.saa.2006.08.044. Epub 2006 Sep 5.

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验