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catena-Poly[[[N-(4-amino-1,6-dihydro-1-methyl-5-nitroso-6-oxopyrimidin-2-yl)-(S)-glutamato]hexaaquabarium]-mu-N-(4-amino-1,6-dihydro-1-methyl-5-nitroso-6-oxopyrimidin-2-yl)-(S)-glutamato]: coordination polymer chains linked into a three-dimensional framework by N-H...O and O-H...O hydrogen bonds.

作者信息

López Garzón Rafael, López León M Dolores, Low John N, Glidewell Christopher

机构信息

Departamento de Química Inorgánica y Orgánica, Universidad de Jaén, 23071 Jaén, Spain.

出版信息

Acta Crystallogr C. 2005 May;61(Pt 5):m224-7. doi: 10.1107/S0108270105008474. Epub 2005 Apr 23.

DOI:10.1107/S0108270105008474
PMID:15876704
Abstract

In the title complex, [Ba(C10H12N5O6)2(H2O)6]n, the Ba atom is nine-coordinated by six water ligands and three carboxylate O atoms. The Ba2+ cations and the anionic glutamate ligands form coordination polymer chains, and these chains are linked by pairs of N-H...O hydrogen bonds and pairs of O-H...O hydrogen bonds to form a continuous three-dimensional framework of cations and anions, which is reinforced by hydrogen bonds involving the water molecules.

摘要

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