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catena-Poly[[(1,10-phenanthroline-kappa(2)N,N')manganese(II)]-di-mu-salicylato-kappa(4)O:O'].

作者信息

Su Jian Rong, Xu Duan Jun

机构信息

Department of Chemistry, Zhejiang University, People's Republic of China.

出版信息

Acta Crystallogr C. 2005 Jun;61(Pt 6):m256-8. doi: 10.1107/S0108270105011078. Epub 2005 May 13.

DOI:10.1107/S0108270105011078
PMID:15930657
Abstract

In the title polymeric complex, [Mn(C7H5O3)2(C12H8N2)]n, the MnII atom is located on a twofold axis and displays a distorted octahedral coordination geometry, formed by four salicylate anions and one 1,10-phenanthroline (phen) molecule. The salicylate anions doubly bridge the Mn(II) atoms to form one-dimensional polymeric chains. A comparison of Mn-O bond distances with the corresponding Mn-O-C angles suggests a significant electrostatic content in the Mn-O bonds. A face-to-face distance of 3.352 (7) A between neighbouring parallel phen planes indicates pi-pi stacking interactions between polymeric chains.

摘要

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