水合 -（2,9 - 二甲基 - 1,10 - 菲咯啉 - κN,N'）双 -（3 - 羟基苯甲酸根 - κO）锰（II）- 2,9 - 二甲基 - 1,10 - 菲咯啉 - 水（1/1/1）
Aqua-(2,9-dimethyl-1,10-phenanthroline-κN,N')bis-(3-hydroxy-benzoato-κO)manganese(II)-2,9-dimethyl-1,10-phenanthroline-water (1/1/1).
作者信息
Liu Xuejun, Jin Linyu
机构信息
College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475001, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 11;65(Pt 8):m901. doi: 10.1107/S1600536809025926.
In the title compound, [Mn(C(7)H(5)O(3))(2)(C(14)H(12)N(2))(H(2)O)]·C(14)H(12)N(2)·H(2)O, the Mn(II) ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand, two monodentate 3-hydroxy-benzoate anions (3-HBA) and one water mol-ecule in a distorted trigonal-bipyramidal environment. An uncoordinated dmphen and an uncoordinated water mol-ecule cocrystallized with each complex mol-ecule. Intra- and inter-molecular O-H⋯N and O-H⋯O hydrogen bonds are also present between the coordinated 3-HBA and water mol-ecules and the uncoordinated dmphen and water mol-ecules in the crystal. The packing of the structure is further stabilized by π-π stacking inter-actions involving dmphen mol-ecules, with a centroid-centroid separation of 3.705 (3) Å.
在标题化合物[Mn(C₇H₅O₃)₂(C₁₄H₁₂N₂)(H₂O)]·C₁₄H₁₂N₂·H₂O中，Mn(II)离子在扭曲的三角双锥环境中由一个双齿的2,9 - 二甲基 - 1,10 - 菲咯啉（dmphen）配体、两个单齿的3 - 羟基苯甲酸根阴离子（3 - HBA）和一个水分子配位。一个未配位的dmphen和一个未配位的水分子与每个配合物分子共结晶。在晶体中，配位的3 - HBA和水分子与未配位的dmphen和水分子之间还存在分子内和分子间的O - H⋯N和O - H⋯O氢键。结构的堆积通过涉及dmphen分子的π - π堆积相互作用进一步稳定，质心 - 质心间距为3.705 (3) Å。
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