壮观霉素的全合成及其向SNF4435C和SNF4435D的仿生转化。
The total synthesis of spectinabilin and its biomimetic conversion to SNF4435C and SNF4435D.
作者信息
Jacobsen Mikkel F, Moses John E, Adlington Robert M, Baldwin Jack E
机构信息
Chemistry Research Laboratory, University of Oxford, Mansfield Road, Oxford, OX1 3TA, United Kingdom.
出版信息
Org Lett. 2005 Jun 9;7(12):2473-6. doi: 10.1021/ol0507874.
PMID:15932226
Abstract
[reaction: see text] A short synthesis of (+/-)-spectinabilin via a trans-selective Suzuki coupling and subsequent Negishi-type methylation, and its biomimetic conversion to (+/-)-SNF4435C and (+/-)-SNF4435D is described.
摘要
[反应：见正文] 描述了通过反式选择性铃木偶联和随后的根岸型甲基化对（±）-壮观菌素进行的简短合成，以及其仿生转化为（±）-SNF4435C和（±）-SNF4435D的过程。
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