• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

Highly electrophilic, 16-electron [Ru(P(OMe)(OH)(2))(dppe)(2)](2+) complex turns H(2)(g) into a strong acid and splits a Si-H bond heterolytically. Synthesis and structure of the novel phosphorous acid complex [Ru(P(OH)(3))(dppe)(2)](2+).

作者信息

Nagaraja C M, Nethaji Munirathinam, Jagirdar Balaji R

机构信息

Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012, India.

出版信息

Inorg Chem. 2005 Jun 13;44(12):4145-7. doi: 10.1021/ic050026x.

DOI:10.1021/ic050026x
PMID:15934741
Abstract

The highly electrophilic, 16-electron, coordinatively unsaturated [Ru(P(OMe)(OH)(2))(dppe)(2)]OTf complex brings about the heterolytic activation of H(2)(g) and spontaneously generates HOTf. In addition, trans-Ru(H)(P(OMe)(OH)(2))(dppe)(2) and an unprecedented example of a phosphorous acid complex, Ru(P(OH)(3))(dppe)(2), are formed. The [Ru(P(OMe)(OH)(2))(dppe)(2)]OTf complex also cleaves the Si-H bond in EtMe(2)SiH in a heterolytic fashion, resulting in the trans-Ru(H)(P(OMe)(OH)(2))(dppe)(2) derivative.

摘要

相似文献

1
Highly electrophilic, 16-electron [Ru(P(OMe)(OH)(2))(dppe)(2)](2+) complex turns H(2)(g) into a strong acid and splits a Si-H bond heterolytically. Synthesis and structure of the novel phosphorous acid complex [Ru(P(OH)(3))(dppe)(2)](2+).
Inorg Chem. 2005 Jun 13;44(12):4145-7. doi: 10.1021/ic050026x.
2
Heterolytic activation of H-X (X = H, Si, B, and C) bonds: an experimental and theoretical investigation.H-X（X = H、Si、B和C）键的异裂活化：一项实验与理论研究。
J Am Chem Soc. 2007 May 2;129(17):5587-96. doi: 10.1021/ja069044j. Epub 2007 Apr 7.
3
C7 and C9 carbon-rich bridges in diruthenium systems: synthesis, spectroscopic, and theoretical investigations of different oxidation States.二钌体系中富含C7和C9的碳桥：不同氧化态的合成、光谱及理论研究
J Am Chem Soc. 2006 May 3;128(17):5859-76. doi: 10.1021/ja0603453.
4
New cationic and zwitterionic Cp*M(kappa2-P,S) complexes (M = Rh, Ir): divergent reactivity pathways arising from alternative modes of ancillary ligand participation in substrate activation.新型阳离子和两性离子 Cp*M(κ²-P,S) 配合物（M = Rh、Ir）：辅助配体参与底物活化的不同模式引发的不同反应途径
J Am Chem Soc. 2008 Dec 3;130(48):16394-406. doi: 10.1021/ja8062277.
5
Reactivity of a coordinatively unsaturated Cp*Ru(kappa2-P,O) complex.
Chem Commun (Camb). 2008 Jan 14(2):250-2. doi: 10.1039/b713386c. Epub 2007 Oct 25.
6
Utilization of CS2 as a source of C1 chemistry for the generation of methyldithioformate.
Inorg Chem. 2003 Aug 11;42(16):4798-800. doi: 10.1021/ic0346937.
7
Synthesis and structure of CpMo(CO)(dppe)H and its oxidation by Ph3C+.CpMo(CO)(dppe)H的合成、结构及其被Ph3C+氧化
Inorg Chem. 2006 Jun 12;45(12):4712-20. doi: 10.1021/ic060111k.
8
Exploring the reactivity of a coordinatively unsaturated Cp*Ru(kappa(2)-P,O) complex with small molecule substrates: application in E-H bond activation (E = H, B, and Si).探索配位不饱和的Cp*Ru(κ(2)-P,O)配合物与小分子底物的反应活性：在E-H键活化中的应用（E = H、B和Si）。
Dalton Trans. 2009 Jun 28(24):4756-65. doi: 10.1039/b903420j. Epub 2009 Apr 16.
9
Insertion reactions of alkynes and organic isocyanides into the palladium-carbon bond of dimetallic Fe-Pd alkoxysilyl complexes.炔烃和有机异腈插入双金属铁 - 钯烷氧基硅基配合物的钯 - 碳键的反应。
Dalton Trans. 2006 Nov 28(44):5248-58. doi: 10.1039/b610324c. Epub 2006 Oct 18.
10
Redox-active organometallics: magnetic and electronic couplings through carbon-silicon hybrid molecular connectors.氧化还原活性有机金属化合物：通过碳-硅杂化分子连接器实现的磁耦合和电子耦合
J Am Chem Soc. 2008 Dec 24;130(51):17372-83. doi: 10.1021/ja804608z.