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用杏核制备的活性炭对水溶液中重金属离子的吸附

Adsorption of heavy metal ions from aqueous solutions by activated carbon prepared from apricot stone.

作者信息

Kobya M, Demirbas E, Senturk E, Ince M

机构信息

Department of Environmental Engineering, Gebze Institute of Technology, Turkey.

出版信息

Bioresour Technol. 2005 Sep;96(13):1518-21. doi: 10.1016/j.biortech.2004.12.005. Epub 2005 Feb 25.

Abstract

Apricot stones were carbonised and activated after treatment with sulphuric acid (1:1) at 200 degrees C for 24 h. The ability of the activated carbon to remove Ni(II), Co(II), Cd(II), Cu(II), Pb(II), Cr(III) and Cr(VI) ions from aqueous solutions by adsorption was investigated. Batch adsorption experiments were conducted to observe the effect of pH (1-6) on the activated carbon. The adsorptions of these metals were found to be dependent on solution pH. Highest adsorption occurred at 1-2 for Cr(VI) and 3-6 for the rest of the metal ions, respectively. Adsorption capacities for the metal ions were obtained in the descending order of Cr(VI) > Cd(II) > Co(II) > Cr(III) > Ni(II) > Cu(II) > Pb(II) for the activated carbon prepared from apricot stone (ASAC).

摘要

杏核经硫酸(1:1)在200℃处理24小时后进行碳化和活化。研究了活性炭通过吸附从水溶液中去除镍(II)、钴(II)、镉(II)、铜(II)、铅(II)、铬(III)和铬(VI)离子的能力。进行了批量吸附实验以观察pH值(1 - 6)对活性炭的影响。发现这些金属的吸附取决于溶液的pH值。铬(VI)在pH值为1 - 2时吸附量最高,其余金属离子在pH值为3 - 6时吸附量最高。对于由杏核制备的活性炭(ASAC),金属离子的吸附容量按铬(VI)>镉(II)>钴(II)>铬(III)>镍(II)>铜(II)>铅(II)的顺序递减。

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