芳炔与碳-碳σ键的简易插入反应。
Facile insertion reaction of arynes into carbon-carbon sigma-bonds.
作者信息
Yoshida Hiroto, Watanabe Masahiko, Ohshita Joji, Kunai Atsutaka
机构信息
Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima 739-8527, Japan.
出版信息
Chem Commun (Camb). 2005 Jul 14(26):3292-4. doi: 10.1039/b505392g. Epub 2005 Jun 1.
DOI:10.1039/b505392g
PMID:15983651
Abstract
The carbon-carbon sigma-bond of various beta-dicarbonyl compounds was found to add to the triple bond of arynes under extremely mild conditions, leading to direct introduction of different carbon functional groups into the aromatic skeletons.
摘要
人们发现，各种β-二羰基化合物的碳-碳σ键在极其温和的条件下可加成到芳炔的三键上，从而将不同的碳官能团直接引入到芳香骨架中。
Zotero 插件