Tambar Uttam K, Ebner David C, Stoltz Brian M
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, USA.
J Am Chem Soc. 2006 Sep 13;128(36):11752-3. doi: 10.1021/ja0651815.
A convergent and enantioselective synthesis of the natural product amurensinine is described. The synthetic strategy takes advantage of mild and selective C-H and C-C bond insertion reactions, in addition to the palladium-catalyzed aerobic oxidative kinetic resolution recently developed in these laboratories.
本文描述了天然产物木兰辛宁的对映选择性汇聚合成。该合成策略利用了温和且选择性的C-H和C-C键插入反应,以及最近在这些实验室中开发的钯催化需氧氧化动力学拆分反应。