Aymonier Cyril, Elissalde Catherine, Reveron Helen, Weill François, Maglione Mario, Cansell François
Institut de Chimie de la Matière Condensée de Bordeaux 87, Avenue du Dr A. Schweitzer, 33608 Pessac, Cedex, France.
J Nanosci Nanotechnol. 2005 Jun;5(6):980-3. doi: 10.1166/jnn.2005.147.
This work highlights, for the first time, the coating of ferroelectric nanoparticles with a chemical fluid deposition process in supercritical fluids. BaTiO3 nanoparticles of about 50 nm are coated with a shell of a few nanometers of amorphous alumina and can be recovered as a dry powder for processing. The sintering of these core-shell nanoparticles gives access to a ceramic material with very interesting ferroelectric properties, in particular, dielectric losses below 1%.
这项工作首次突出了在超临界流体中通过化学流体沉积工艺对铁电纳米颗粒进行包覆。约50纳米的钛酸钡纳米颗粒被包覆了几层纳米厚的非晶态氧化铝外壳,并且可以作为干粉回收用于加工。这些核壳纳米颗粒的烧结能够得到一种具有非常有趣的铁电性能的陶瓷材料,特别是介电损耗低于1%。