一种由铜配合物平面阵列夹着的二维笼形水合物。
A two-dimensional clathrate hydrate sandwiched by planar arrays of a copper complex.
作者信息
Miyamoto Riichi, Hamazawa Rika Tanaka, Hirotsu Masakazu, Nishioka Takanori, Kinoshita Isamu, Wright L James
机构信息
Department of Molecular Materials Science, Osaka City University, 3-3-138 Sugimoto, Osaka 558-8585, Japan.
出版信息
Chem Commun (Camb). 2005 Aug 28(32):4047-9. doi: 10.1039/b505681k. Epub 2005 Jun 15.
The first structurally characterised example of a 2-D clathrate hydrate spontaneously assembles when [CuF(tptm)] (tptm = tris(2-pyridylthio)methyl) crystallises from toluene/water solutions to produce a material in which planar arrays of [CuF(tptm)] sandwich and hydrogen bond to continuous 2-D sheets of water that incorporate toluene molecules at regular intervals.
当[CuF(tptm)]（tptm = 三(2-吡啶硫基)甲基）从甲苯/水溶液中结晶时，首个结构特征明确的二维笼形水合物的例子会自发组装，生成一种材料，其中[CuF(tptm)]的平面阵列夹在中间，并与连续的二维水层形成氢键，这些水层以规则间隔包含甲苯分子。
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