Wang Yueh-Ju, Song Jian-Hong, Lin Yu-Siang, Lin Ching, Sheu Hwo-Shuenn, Lee Gene-Hsiang, Lai Chung K
Department of Chemistry, National Central University, & Center for Nano Science Technology, UST, Chung-Li, Taiwan 32054, ROC.
Chem Commun (Camb). 2006 Dec 21(47):4912-4. doi: 10.1039/b612374k. Epub 2006 Oct 9.
The first example of supramolecular metallomesogens derived from palladium complexes exhibiting columnar phase is reported, and the formation of the mesophase is induced by H-bonding in a tetrameric assembly.
报道了首例源自钯配合物且呈现柱状相的超分子金属液晶的实例,并且在四聚体组装体中通过氢键作用诱导形成中间相。