钌（IV）催化的烯丙胺在水中的异构化反应：一种用于N-烯丙基胺脱保护的高效方法。
Ru(IV)-catalyzed isomerization of allylamines in water: a highly efficient procedure for the deprotection of N-allylic amines.
作者信息
Cadierno Victorio, García-Garrido Sergio E, Gimeno José, Nebra Noel
机构信息
Departamento de Química Orgánica e Inorgánica, Instituto Universitario de Química Organometálica Enrique Moles (Unidad Asociada al C.S.I.C.), Universidad de Oviedo, 33071, Oviedo, Spain.
出版信息
Chem Commun (Camb). 2005 Aug 28(32):4086-8. doi: 10.1039/b506788j. Epub 2005 Jul 13.
DOI:10.1039/b506788j
PMID:16091808
Abstract
A general and efficient method for the deprotection of N-allylic substrates in aqueous media, using catalytic amounts of the bis(allyl)-ruthenium(IV) complexes [Ru(eta3:eta2:eta3-C12H18)Cl2] and [{Ru(eta3:eta3-C10H16)(micro-Cl)Cl}2], has been developed.
摘要
已开发出一种通用且高效的方法，用于在水性介质中对N-烯丙基底物进行脱保护，该方法使用催化量的双(烯丙基)-钌(IV)配合物[Ru(η³:η²:η³-C₁₂H₁₈)Cl₂]和[{Ru(η³:η³-C₁₀H₁₆)(μ-Cl)Cl}₂]。
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