钯催化的三组分环化反应一锅法合成高度取代的呋喃
Palladium-catalyzed one-pot synthesis of highly substituted furans by a three-component annulation reaction.
作者信息
Duan Xin-hua, Liu Xue-yuan, Guo Li-na, Liao Meng-chun, Liu Wei-Min, Liang Yong-min
机构信息
State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P.R. China.
出版信息
J Org Chem. 2005 Aug 19;70(17):6980-3. doi: 10.1021/jo050908d.
PMID:16095331
Abstract
A new three-component cyclization-coupling reaction catalyzed by palladium was developed, producing polysubstituted furans in good yields from readily available substrates. The reaction conditions and the scope of the process were examined, and a possible mechanism is proposed.
摘要
开发了一种由钯催化的新型三组分环化偶联反应，该反应能以良好的产率从易得的底物生成多取代呋喃。研究了该反应的条件和过程范围，并提出了一种可能的机理。
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