Meier Robert J
Institute of Chemistry and Dynamics of the Geosphere IV: Agrosphere, Forschungszentrum Jülich GmbH D-52425 Jülich, Germany.
Chem Soc Rev. 2005 Sep;34(9):743-52. doi: 10.1039/b503880d. Epub 2005 Jul 19.
The aim of this tutorial review is to convince a broad readership that vibrational spectroscopy, although according to some vibrational spectroscopists seemingly less in focus nowadays than in days past, is far from 'dead'. It may seem to some that infrared and Raman spectroscopy are less in focus than in times past, despite the unique analytical capabilities. Vibrational spectroscopy is particularly powerful for non-destructive characterisation of substances, including living material. But compared to the past, a shift in applications has taken place, bringing new opportunities. This is partly due to the introduction of new features, including imaging and 2D correlation spectroscopy. Another factor is the recognition that vibrational spectroscopy can play a role in new rather than only in the traditional fields of application, e.g. new applications in the life-science field (living cells, cancer research), the characterisation of soil. But also the traditional application in catalysis sees new development within the context of Operando spectroscopy.
本教程综述的目的是让广大读者相信,振动光谱学虽然在一些振动光谱学家看来,如今似乎不如过去受关注,但远未“过时”。对一些人来说,尽管红外光谱和拉曼光谱具有独特的分析能力,但它们如今似乎不如过去受关注。振动光谱学对于物质(包括生物材料)的无损表征特别有效。但与过去相比,应用领域发生了转变,带来了新的机遇。这部分是由于引入了新特性,包括成像和二维相关光谱学。另一个因素是认识到振动光谱学不仅能在传统应用领域发挥作用,还能在新的领域发挥作用,例如生命科学领域(活细胞、癌症研究)的新应用、土壤表征。而且,在原位光谱学的背景下,催化领域的传统应用也有了新的发展。