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一种用于环氧丙烷聚合的高活性、等规钴催化剂。

A highly active, isospecific cobalt catalyst for propylene oxide polymerization.

作者信息

Peretti Kathryn L, Ajiro Hiroharu, Cohen Claire T, Lobkovsky Emil B, Coates Geoffrey W

机构信息

Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853-1301, USA.

出版信息

J Am Chem Soc. 2005 Aug 24;127(33):11566-7. doi: 10.1021/ja053451y.

DOI:10.1021/ja053451y
PMID:16104709
Abstract

A highly active cobalt complex ((salph)CoOAc; salph = N,N'-bis(3,5-di-tert-butylsalicylidine-1,2-benzenediamine)) was discovered for the isospecific polymerization of rac-propylene oxide.

摘要

一种高活性钴配合物（(salph)CoOAc；salph = N,N'-双(3,5-二叔丁基水杨醛缩-1,2-苯二胺)）被发现可用于外消旋环氧丙烷的等规聚合反应。

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