Ito Seigo, Liska Paul, Comte Pascal, Charvet Raphaël, Péchy Peter, Bach Udo, Schmidt-Mende Lukas, Zakeeruddin Shaik Mohammed, Kay Andreas, Nazeeruddin Mohammad K, Grätzel Michael
Laboratoire de Photonique et Interfaces, Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne, Station 6, CH-1015 Lausanne, Switzerland.
Chem Commun (Camb). 2005 Sep 14(34):4351-3. doi: 10.1039/b505718c. Epub 2005 Aug 2.
The ruthenium complex bis-tetrabutylammonium cis-dithiocyanato-N,N'-bis-2,2'-bipyridine-4-carboxylic acid, 4'-carboxylate ruthenium(II), N-719, was found to block the dark current of dye sensitized solar cells (DSC), based on mesoporous TiO2 films deposited on a F-doped tin oxide electrode and the effect was compared to surface treatment by TiCl4 and the introduction of a compact TiO2 blocking layer.
钌配合物双四丁基铵顺式二硫氰酸根-N,N'-双-2,2'-联吡啶-4-羧酸、4'-羧酸根钌(II),即N-719,被发现可阻断基于沉积在氟掺杂氧化锡电极上的介孔二氧化钛薄膜的染料敏化太阳能电池(DSC)的暗电流,并将该效果与用四氯化钛进行表面处理以及引入致密二氧化钛阻挡层的效果进行了比较。